Sec.304:

EPA SARA Title III Section 304: CERCLA Reportable + Sec.302 with Reportable Quantity. **
indicates statutory RQ.

Sec.313:

EPA SARA Title III Section 313 Toxic Release Inventory. Note: -Cat indicates a member of a
chemical category.

Sec.110:

EPA SARA 110 Superfund Site Priority Contaminant List

TSCA (Toxic Substances Control
Act) Lists:
Inventory:

Licensed to Excelda Manufacturing, Inc.

Chemical Listed in the TSCA Inventory.

ANSI Z400.1 format

MATERIAL SAFETY DATA SHEET
Cooling System Iron Cleaner
5A(2):

Chemical Subject to Significant New Rules (SNURS)

6A:

Commercial Chemical Control Rules

8A:

Toxic Substances Subject To Information Rules on Production

8A CAIR:

Comprehensive Assessment Information Rules - (CAIR)

8A PAIR:

Preliminary Assessment Information Rules - (PAIR)

8C:

Records of Allegations of Significant Adverse Reactions

8D:

Health and Safety Data Reporting Rules

8D TERM:

Health and Safety Data Reporting Rule Terminations

12(b):

Notice of Export

Page: 5
Printed: 10/28/2013
Revision: 10/18/2013

Other Important Lists:
CWA NPDES:

EPA Clean Water Act NPDES Permit Chemical

CAA HAP:

EPA Clean Air Act Hazardous Air Pollutant

CAA ODC:

EPA Clean Air Act Ozone Depleting Chemical (1=CFC, 2=HCFC)

CA PROP 65:

California Proposition 65

International Regulatory Lists:
EPA Hazard Categories:

This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated:
[X] Yes [ ] No Acute (immediate) Health Hazard
[ ] Yes [X] No Chronic (delayed) Health Hazard
[ ] Yes [X] No Fire Hazard
[ ] Yes [X] No Sudden Release of Pressure Hazard
[ ] Yes [X] No Reactive Hazard
Regulatory Information

TSCA: All ingredients in this product are listed on the TSCA Inventory or are otherwise exempt.
CA Prop 65: This product is known to contain chemicals known to the State of California to cause cancer, birth
defects or other reproductive harm.
Regulatory Information Statement

The information contained herein is based on data considered accurate. However, no warranty is expressed or
implied regarding the accuracy of this data or the results to be obtained from the use thereof. Vendor assumes no
responsibility for injury to vendee or third person proximately caused by the material if reasonable safety
procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for
injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable safety
procedures are followed. Furthermore, vendee assumes all risk in use of the material.

16. Other Information
Company Policy or Disclaimer

THIS INFORMATION IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED, EXCEPT
THAT IS ACCURATE TO THE BEST KNOWLEDGE OF HINO MOTOR SALES USA. THE DATA ON
THIS SHEET RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN. HINO MOTOR
SALES USA. ASSUMES NO LEGAL RESPONSIBILITY FOR USE OR RELIANCE UPON THIS DATA.

Licensed to Excelda Manufacturing, Inc.

ANSI Z400.1 format

Excelda reference:GSC-0042-11

Hino Part Number: HP-LLC-01

Material Safety Data Sheet
MSDS No.
Date :

20280
1/9/2013

Page 1 of
5
HINO LLC-EX SUPER COOLANT

HINO LLC-EX SUPER COOLANT
Emergency Number :
Chemtrec : 800/424-9300

General Information :
CCI : 630/739-0606

SECTION I - IDENTIFICATION
Product :

HINO LLC-EX SUPER COOLANT

Synonyms :
Chemical Family :
CAS No. :

None
Ethylene Glycol solution of salts
Mixture - no single CAS number applicable
SECTION II - INGREDIENTS

Components

CAS No.

Nominal %

Ethylene
Glycol

107-21-1

45 - 50 %

Hydrated
inorganic
acid, organic
acid salts

proprietary

Less than 5%

Water

7732-18-5

45 - 50 %

Bittering
agent

proprietary

Note 1

Hazard
Code
A

PEL/TLV

Hazard

Ceiling :
100mg/m
[Aerosol only]

Respiratory irritant
Ingestion may produce
liver, brain and kidney
damage.

N/A

None

None noted.

N/A

None

None noted

Not
established

Skin, eye and
respiratory irritant

A

Note 1 : The degree of aversion of the bittering agent meets or exceeds the degree of aversion in test subjects obtained by
utilizing the formulation of 30 parts per million of denatonium benzoate in antifreeze.

MSDS No.
Date :

20280
1/9/2013

Page 2 of
5
HINO LLC-EX SUPER COOLANT

SECTION III - HEALTH INFORMATION
Inhalation

:

Breathing excessive levels of the vapor or mist can irritate the respiratory tract.
Excessive vapor concentrations of the major component (ethylene glycol),
as might be generated during heating of this material, have occasionally been reported
to cause adverse effects on the blood - forming system and the nervous system.

Ingestion

:

The acute oral toxicities of the components of this mixture are as follows :
Ethylene Glycol
The lowest dose reported to produce death in humans was estimated to be 710
mg/kg body weight; for a person weighting 150 pounds, this would be
equivalent to drinking about one and one-half (1.5) fluid ounces of pure ethylene
glycol in a short period of time.
Acute oral LD50's = 4,700 mg/kg (rat)
5,500 mg/kg (mouse)

Eye Contact

:

Based on the pH and irritation potential of this mixture's constituents, the mist or
liquid can be expected to cause mild to moderate irritation or inflammation of the eyes.

Skin contact

:

The acute dermal LD50 of the major component(ethylene glycol) of this product is
11.89g/kg(rabbits). Based on the pH and the irritation potential of this mixture's
constituents, the mist or liquid can be expected to cause mild to moderate irritation of
the skin.

Carcinogenicity
Listing

IARC : (

)

OSHA : (

)

NTP : (

)

Not listed :

( X )

SECTION IV - OCCUPATIONAL EXPOSURE LIMITS
PEL(OSHA Permissible Exposure Limit) :
TLV(ACGIH Threshold Limit Value) :

None established for mixture, See Section II.
None established for mixture, See Section II.

SECTION V - EMERGENCY FIRST AID PROCEDURE
For Overdose Exposure By :
Swallowing

:

If victim is conscious and able to swallow, quickly have victim drink water or milk to
dilute. Do NOT give sodium bicarbonate, fruit juices or vinegar. NEVER give anything
by mouth if victim is unconscious or having convulsions. Induce vomiting only if
advised by physician or Poison Control Center. CALL PHYSICIAN OR POISON
CONTROL CENTER IMMEDIATELY.

Skin Contact :

Immediately flush skin with plenty of water while removing contaminated clothing.

Eye Contact

:

Immediately flush eyes with plenty of cool water for at least 15 minutes. Do NOT
permit victim to rub eyes. GET MEDICAL ATTENTION IMMEDIATELY.

Inhalation

:

Immediately remove victim to fresh air. If victim has stopped breathing give artificial
respiration, preferably mouth-to-mouth. GET MEDICAL ATTENTION
IMMEDIATELY.

MSDS No.
Date :

20280
1/9/2013

Page 3 of
5
HINO LLC-EX SUPER COOLANT

SECTION VI - PHYSICAL DATA
Boiling Point :

108 °C

Melting Point :

(Freezing Point) less than 0°C

Vapor Pressure :

Estimated 0.05 mmHg at 20°C

Density (20°C) :

1.08 g/cm3

Vapor Density (Air = 1) :

Not determined

pH (Original) :

7.6

Solubility in Water :

Infinite miscibility

Appearance and Color :

Clear, slightly viscous, pink dyed liquid

SECTION VII - FIRE AND EXPLOSION HAZARDS
Flash Point

:

None

Auto-Ignition Temperature :

Not determined (400°C for ethylene glycol)

Flammable Limits in Air, %by Vol.
Lower :
Upper :

Not determined (3.2% for ethylene glycol)
Not determined (15.3% for ethylene glycol)

NFPA Rating :

Health (1) Fire (0) Reactivity (0)

Fire Fighting Procedures :

(Note : Individuals should perform only those firefighting
procedures for which they have been trained.) Use water spray,
dry chemical, foam or carbon dioxide. Use water to keep
fire-exposed containers cool. If a spill or leak has not ignited, use
water spray to disperse the vapors. Water spray may be used to
flush spills away from fire and diluted spills to noncombustible
proportions(see warning on water spray on hot glycol below.)

Unusual Fire & Explosion Hazards :

Fire fighters should wear self-contained breathing apparatus in
the positive pressure mode with a full face piece when, there is a
possibility of exposure to smoke, fumes or hazardous
decomposition products. Water spray may cause foaming of hot
glycol so indirect application of water spray or use of other
extinguishing media should be used on hot glycol.

SECTION VIII - REACTIVITY
Stability

:

Generally stable

Hazardous Polymerization :

Not likely to occur

Conditions and Materials to Avoid :

Avoid concentrated strong acids, oxidizing agents and bases. Do
not expose to open flame.

Hazardous Decomposition Products :

If pyrolyzed, thermal decomposition products of residue may
include C, CO, CO2, H2O, NH3, organic vapors and
nitrogen-containing.

MSDS No.
Date :

20280
1/9/2013

Page 4 of
5
HINO LLC-EX SUPER COOLANT

SECTION IX - EMPLOYEE PROTECTION
Control Measures :

Handle in the presence of adequate ventilation. Engineering controls should
be used whenever feasible to maintain concentrations below acceptable
exposure criteria (see Section II and IV), including enclosures and local
exhaust ventilation.

Respiratory Protection :

Where exposure is likely to exceed acceptable criteria (see Section II and IV)
and engineering controls are not feasible, use NIOSH/MSHA approved
respiratory protection equipment. Respirators should be selected based on the
form and concentration of contaminants in air and in accordance with OSHA
(29 CFR 1910.134)

Protective Clothing :

Wear gloves and protective clothing which are impervious to the product for
the duration of exposure if there is potential for skin contact.

Eye Protection :

Wear safety glasses meeting the specifications of ANSI Standard Z87.1 where
no contact with the eye is anticipated. Chemical safety goggles meeting the
specification of ANSI Standard Z87.1 should be worn whenever there is the
possibility of splashing or other contact with the eyes.

SECTION X - ENVIRONMENTAL PROTECTION
Environmental Precautions :

Avoid uncontrolled releases of this material. Where spills are possible, a
comprehensive spill release response plan should be developed and
implemented.

Spill or Leak Procedures :

Wear appropriate respiratory equipment and protective equipment as
described in Section IX. Contain spilled material. Transfer to secure
containers. Where necessary, collect using absorbent media. In the event
of an uncontrolled release is reportable under the applicable laws and
regulations.

Waste Disposal :

All recovered material should be packaged, labeled, transported, and
disposed of or reclaimed in conformance with good engineering practices.
Avoid land filling of liquids. Reclaim where possible.

SECTION XI - REGULATORY CONTROLS
Department of Transportation :
DOT Classification (Bulk) :

Class 9 miscellaneous

DOT Proper Shipping Name :

Environmentally Hazardous Substance Liquid n.o.s.
(ethylene glycol), 9, UN3082, III

DOT Classification (Non-bulk) :

Not regulated

IATA (Non-bulk) :

Not regulated

IMDG Code (Non-bulk) :

Not regulated

Other Regulatory Requirements :
Toxic Substance Control Act

:

This product is a mixture : therefore, it is not listed in the TSCA Inventory of
Chemical Substances. All of the components of the mixture are listed in the TSCA
Inventory of Chemical Substances.
SARA Hazard Categories (as defined in Section 311/312)

MSDS No.
Date :

20280
1/9/2013

Page 5 of
5
HINO LLC-EX SUPER COOLANT

SECTION XI - REGULATORY CONTROLS(CONTINUED)
Health

Immediate (Acute) and Delayed (Chronic)

Physical

None
The product contains greater than 40% ethylene glycol (CAS# 107-21-1)
which is subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372.

California Proposition 65
This product does not contain any substances currently listed under California
Proposition 65.
Bitterant Agent
This product contains bitterant agent.

SECTION XII - PRECAUTIONS : HANDLING, STORAGE AND USAGE
- To prevent possible storage container rupture, do not permit to freeze; See Section VI.
- Do not expose children and pets to this material.
- Keep container closed.
- Keep away from open flames.
- After handling product, wash thoroughly with soap and water before drinking, eating, or
smoking.
- Container hazardous when emptied. Since emptied containers retain product residues, all
hazardous precautions described on this MSDS must be observed.

SECTION XIII - CONTACT INFORMATION
The information presented herein is believed to be factual as it has been derived from the works and
opinions of people believed to be qualified experts; however, nothing contained in this information is to
be taken as a warranty or representation for which CCI Manufacturing IL Corporation bears legal
responsibility. The user should review any recommendation in the specific context of intended use to
determine whether they are appropriate.
Prepared By

CCI MANUFACTURING IL CORPORATION

For further information contact :
Technical Manager
CCI MANUFACTURING IL CORPORATION
15550 Canal Bank Rd
Lemont, IL 60439
(630)-739-0606