NHTSA ID Number: 10183823
Manufacturer Communication Number: 114484 AUS 32
TSB/Document Date: 2020-12-07
Summary
SAFETY DATA SHEET AUS 32 Urea Solution
SAFETY DATA SHEET
AUS 32 Urea Solution
Page: 1
Printed: 09/15/2015
Revision: 01/15/2015
1. PRODUCT AND COMPANY IDENTIFICATION
Product Code:
Product Name:
Reference #:
Company Name:
114484-RM-GHS
AUS 32 Urea Solution
805-114484
Excelda Manufacturing
12785 Emerson Dr.
Brighton, MI 48116
Emergency Contact:
Information:
Phone Number:
(248)486-3800
MEDICAL EMERGENCY
DOT EMERGENCY
INFORMATION
(888)314-4052
(800)424-9300
(248)486-3800
2. HAZARDS IDENTIFICATION
Skin Corrosion/Irritation, Category 3
GHS Signal Word:
GHS Hazard Phrases:
Warning
H316: Causes mild skin irritation.
GHS Precaution Phrases:
No phrases apply.
GHS Response Phrases:
P332+313: If skin irritation occurs, get medical advice/attention.
GHS Storage and Disposal
Phrases:
No phrases apply.
Potential Health Effects
(Acute and Chronic):
May cause slight irritation to eyes and skin. May generate fumes which may irritate
respiratory system. If heated, may generate ammonia or other harmful or otherwise
toxic fumes which may cause irritation or other harm to lungs.
Inhalation:
Inhalation of large amounts of mist may cause mucous membrane irritation.
Skin Contact:
Prolonged or excusive contact may cause skin irritation.
Eye Contact:
Liquid or mist may cause discomfort in the eye with persistent conjunctivitis, seen as
slight excess redness or conjunctiva.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
Medical Conditions Generally None known.
Aggravated By Exposure:
3. COMPOSITION/INFORMATION ON INGREDIENTS
CAS #
Chemical Name
Concentration
RTECS #
Molecular Formula
7732-18-5
Water
66.0 -69.0 %
ZC0110000 H2O
57-13-6
Urea
31.0 -33.5 %
YR6250000 H2NCONH2
Additional Chemical
Information
Licensed to Excelda Manufacturing, Inc.
GHS format
SAFETY DATA SHEET
AUS 32 Urea Solution
Page: 2
Printed: 09/15/2015
Revision: 01/15/2015
4. FIRST AID MEASURES
Emergency and First Aid
Procedures:
In Case of Inhalation:
If irritation develops move patient to fresh air and monitor. If cough or difficulty in
breathing develops, evaluate for respiratory tract irritation. If trained to do so, administer
supplemental oxygen if needed and seek medical attention.
In Case of Skin Contact:
Flush exposed area with copious amounts of water followed by washing area thoroughly
with soap and water. Seek medical attention if irritation or pain persists.
In Case of Eye Contact:
Flush eyes with copious amounts of tepid water for at least 15 minutes. Seek medical
attentino if irritation, pain, swelling, excessive tearing, or light sensitivity persists.
In Case of Ingestion:
If conscious, give the patient large quantities of water to drink and seek medical
attention immediately. Do not give anything by mouth to an unconscious person.
Signs and Symptoms Of
Exposure:
Irritation, redness or other discomfort.
Note to Physician:
Treat symptoms.
5. FIRE FIGHTING MEASURES
Flash Pt:
> 200.00 F (93.3 C)
Explosive Limits:
LEL: No data.
Autoignition Pt:
No data.
Suitable Extinguishing
Media:
As appropriate for surrounding fire.
Unsuitable Extinguishing
Media:
None known.
Fire Fighting Instructions:
As for all fires involving chemicals, responders should wear full bunker gear including a
positive pressure self-contained breathing apparatus (SCBA). Cool containers with
water spray to prevent the generation of harmful/toxic fumes which may generate
pressure and cause containers to burst releasing the harmful fumes.
Flammable Properties and
Hazards:
Urea solution is not flammable, however, when heated, urea releases ammonia and
when heated to decomposition it emits toxic fumes of nitrogen oxides (NOx), ammonia,
and cyanuric acid.
Method Used: Pensky-Marten Closed Cup
UEL: No data.
Reacts with sodium hypochlorite or calcium hypochlorite to form the explosive nitrogen
trichloride.
6. ACCIDENTAL RELEASE MEASURES
Protective Precautions,
Protective Equipment and
Emergency Procedures:
As appropriate for size and nature of spill. See Section 8 for recommended PPE.
Steps To Be Taken In Case
Material Is Released Or
Spilled:
Spill or Leak Measures: Spilled urea solution may cause slippery conditions. Keep
unnecessary people away and isolate hazard area. Contain spill to prevent run-off.
Recover as much liquid as possible, then removing remainder by absorbing with inert
material. Place recovered liquid and absorbed liquid in container for proper handling
and disposal.
7. HANDLING AND STORAGE
Precautions To Be Taken in Avoid eye and skin contact.
Handling:
Precautions To Be Taken in Store in cool location.
Storing:
Licensed to Excelda Manufacturing, Inc.
GHS format
SAFETY DATA SHEET
AUS 32 Urea Solution
Page: 3
Printed: 09/15/2015
Revision: 01/15/2015
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
CAS #
Partial Chemical Name
OSHA TWA
ACGIH TWA
Other Limits
7732-18-5
Water
No data.
No data.
No data.
57-13-6
Urea
No data.
No data.
No data.
Respiratory Equipment
(Specify Type):
Under expected use, no respiratory equipment is expected to be required. However, as
urea will generate ammonia and carbon dioxide, respiratory equipment may be
necessary in enclosed, or otherwise poorly ventilated areas as they can displace
oxygen. Always check oxygen levels in any area that is not well ventilated. Use an
ammonia filter respirator if ammonia concentrations exceed permissible amounts.
Eye Protection:
It is recommended that safety glasses or goggles be used and if there is a potential for
splashing liquid, a face shield should be used in conjunction with the safety glasses or
goggles.
Protective Gloves:
Impervious gloves such as rubber or neoprene should be worn.
Other Protective Clothing:
As needed to minimize contact with skin.
Engineering Controls
(Ventilation etc.):
Adequate ventilation should be supplied.
Work/Hygienic/Maintenance When using do not eat, drink or smoke. Avoid contact with skin, eyes and clothing.
Wash hands before breaks and at the end of workday. Wash contaminated clothing
Practices:
before re-use.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical States:
Appearance and Odor:
Melting Point:
Boiling Point:
Autoignition Pt:
Flash Pt:
Explosive Limits:
Specific Gravity (Water = 1):
Vapor Pressure (vs. Air or
mm Hg):
Vapor Density (vs. Air = 1):
Evaporation Rate:
Solubility in Water:
pH:
Percent Volatile:
Licensed to Excelda Manufacturing, Inc.
[ ] Gas
[ X ] Liquid
[ ] Solid
Colorless liquid, Slight ammonia odor (pungent)
No data.
No data.
No data.
> 200.00 F (93.3 C) Method Used: Pensky-Marten Closed Cup
LEL: No data.
UEL: No data.
1.087 - 1.095
at 20.0 C (68.0 F)
No data.
No data.
No data.
100%
at 20.0 C (68.0 F)
9.0 - 10.25
No data.
GHS format
SAFETY DATA SHEET
AUS 32 Urea Solution
Page: 4
Printed: 09/15/2015
Revision: 01/15/2015
10. STABILITY AND REACTIVITY
Reactivity:
Urea will form urea nitrate when mixed with nitric acid at low pH. Urea nitrate may
become unstable and/or explosive under certain conditions.
Stability:
Unstable [
Conditions To Avoid Instability:
Avoid hight heat/temperatures and contact with incompatible materials.
]
Stable [ X ]
Incompatibility - Materials To Hypochlorites such as sodium hypochlorite (bleach) or calcium hypochlorite, sodium
nitrate, phosphorus pentachloride, nitrosyl or gallium perchlorate and nitric acid.
Avoid:
Hazardous Decomposition or Urea solution forms ammonia, cyanuric acid, biuret, and/or nitrogen oxides (NOx) upon
decomposition.
Byproducts:
Possibility of Hazardous
Reactions:
Will occur [
Conditions To Avoid Hazardous Reactions:
None known.
]
Will not occur [ X ]
11. TOXICOLOGICAL INFORMATION
Toxicological Information:
No data available.
Irritation or Corrosion:
Excessive contact may cause irritation.
Sensitization:
Does not contain any known sensitizers at levels that may cause an allergic reaction.
Chronic Toxicological
Effects:
None known.
Carcinogenicity/Other
Information:
Does not contain any known carcinogens.
CAS #
Chemical Name
NTP
IARC
ACGIH
OSHA
7732-18-5
Water
n.a.
n.a.
n.a.
n.a.
57-13-6
Urea
n.a.
n.a.
n.a.
n.a.
12. ECOLOGICAL INFORMATION
General Ecological
Information:
Notify local health and wildlife officials and operators of any nearby water intakes of
contamination or discharge into or leading to waterways.
Persistence and
Degradability:
Urea is rapidly hydrolyzed to ammonia and carbon dioxide in environmental systems by
the extracellular enzyme, urease, which originates from microorganisms and plant roots.
13. DISPOSAL CONSIDERATIONS
Waste Disposal Method:
Urea solution is not listed by the Federal EPA as a hazardous waste. Consult
state/provincial and local environmental agencies for acceptable disposal methods. If
permitted and uncontaminated, recover product may be use as a fertilizer.
14. TRANSPORT INFORMATION
LAND TRANSPORT (US DOT):
DOT Proper Shipping Name: Not regulated
DOT Hazard Class:
UN/NA Number:
Licensed to Excelda Manufacturing, Inc.
GHS format
SAFETY DATA SHEET
AUS 32 Urea Solution
Page: 5
Printed: 09/15/2015
Revision: 01/15/2015
15. REGULATORY INFORMATION
EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists
CAS #
Chemical Name
S. 302 (EHS)
S. 304 RQ
S. 313 (TRI)
7732-18-5
Water
No
No
No
57-13-6
Urea
No
No
No
This material meets the EPA
'Hazard Categories' defined
for SARA Title III Sections
311/312 as indicated:
CAS #
[X] Yes
[ ] Yes
[ ] Yes
[ ] Yes
[ ] Yes
[ ] No
[X] No
[X] No
[X] No
[X] No
Acute (immediate) Health Hazard
Chronic (delayed) Health Hazard
Fire Hazard
Sudden Release of Pressure Hazard
Reactive Hazard
Chemical Name
Other US EPA or State Lists
7732-18-5
Water
CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes Inventory; CA PROP.65: No
57-13-6
Urea
CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes Inventory, 8A CAIR; CA PROP.65: No
Regulatory Information:
TSCA: All ingredients are listed on the US TSCA Inventory or are otherwise exempt.
SARA Title III: No ingredients are subject to reporting under SARA 313.
CERCLA Hazardous Substances List: No ingredients listed.
Regulatory Information
Statement:
PROP 65: This product is not known to contain any chemicals that would require
disclosure under California Proposition 65.
The information contained herein is based on data considered accurate. However, no
warranty is expressed or implied regarding the accuracy of this data or the results to be
obtained from the use thereof. Vendor assumes no responsibility for injury to vendee or
third person proximately caused by the material if reasonable safety procedures are not
adhered to as stipulated in the data sheet. Additionally, vendor assumes no
responsibility for injury to vendee or third persons proximately caused by abnormal use
of the material even if reasonable safety procedures are followed. Furthermore, vendee
assumes all risk in use of the material.
16. OTHER INFORMATION
01/15/2015
Revision Date:
Additional Information About No data available.
This Product:
Company Policy or
Disclaimer:
Licensed to Excelda Manufacturing, Inc.
THIS INFORMATION IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR
IMPLIED, EXCEPT THAT IS ACCURATE TO THE BEST KNOWLEDGE OF EXCELDA
MANUFACTURING. THE DATA ON THIS SHEET RELATES ONLY TO THE
SPECIFIC MATERIAL DESIGNATED HEREIN. EXCELDA MANUFACTURING
ASSUMES NO LEGAL RESPONSIBILITY FOR USE OR RELIANCE UPON THIS
DATA.
GHS format
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