MANUFACTURING IL CORPORATION

MATERIAL SAFETY DATA SHEET
MSDS No. 108277
Date : 10/3/2005

Page1 of 6
HINO LLC EX SUPER

HINO LLC EX SUPER
Emergency Number :
Chemtrec : 800/424-9300

General Information :
CCI : 630/739-0606
SECTION I - IDENTIFICATION

Product :

HINO LLC EX SUPER

Synonyms :

None

Chemical Family :

Ethylene Glycol solution of salts

Cas RN :

Mixture - no single Cas number applicable
SECTION II - INGREDIENTS

Components

Cas RN

Nominal %

Hazard
Code
A

Ethylene
Glycol

107-21-1

45 - 50%

Potassium
Hydroxide

1310-58-3

1 – 3%

Hydrated
inorganic
acid, organic
acid salts

proprietary

Less than 5%

N/A

Water

7732-18-5

45 - 50%

N/A

Bittering
agent

proprietary

>30mg/kg

A

A

PEL/TLV

Hazard

No OSHA PEL;
ACGIH TLV
(2004) Ceiling
Limit of 100
mg/m3 for
Aerosol Only

Respiratory irritant
Ingestion may
produce liver, brain
and kidney
damage.

No OSHA PEL;
ACGIH TLV
(2004) Ceiling
Limit of 2 mg/m3
No OSHA PEL
or ACGIH TLV
(2004) has been
established.

Skin, eye and
respiratory irritant.
GI tract salts
inflammation.
None noted.

None

None noted.

Not established

Skin, eye and
respiratory irritant

CCI MANUFACTURING IL CORPORATION
ADDRESS: 15550 CANAL BANK ROAD P.O. BOX 339 LEMONT, IL 60439
PHONE (630) 739-0606・FACSIMILE (630) 739-1116

MSDS No. 108277
Date : 10/3/2005

Page2 of 6
HINO LLC EX SUPER
SECTION III - HEALTH INFORMATION

Inhalation :

Breathing excessive levels of the vapor or mist can irritate the respiratory tract.
Excessive vapor concentrations of the major component (ethylene glycol), as might
be generated during heating of this material, have occasionally been reported to cause
adverse effects on the blood-forming system and the nervous system.

Ingestion :

The acute oral toxicities of the components of this mixture are as follows :
Ethylene Glycol :
The lowest dose reported to produce death in humans was estimated to be 710
mg/kg body weight; for a person weighing 150 pounds, this would be equivalent
to drinking about one and one-half (1.5) fluid ounces of pure ethylene glycol in
a short period of time.
Acute oral LD50's =

Potassium Hydroxide :
Acute oral LD50's=

4,700 mg/kg (rats)
7,500 mg/kg (mice)
2,000 mg/kg (cats)
365 mg/kg (rats)

Diethylene glycol :
Acute oral LD50's =

1,000 mg/kg (humans)
14,800 mg/kg (rats)
9,000 mg/kg (dogs)

Eye Contact : .

Based on the pH and irritation potential of this mixture’s constituents, the mist or
liquid can be expected to cause mild to moderate irritation or inflammation of the eyes

Skin Contact :

The acute dermal LD50 of the major component (ethylene glycol) of this product is
11.89 g/kg(rabbits). Based on the pH and the irritation potential of this mixture’s
constituents, the mist or liquid can be expected to cause mild to moderate irritation of
the skin.

Carcinogenicity
Listing

IARC : (

)

OSHA : (

)

NTP : (

)

Not listed : ( X )

SECTION IV - OCCUPATIONAL EXPOSURE LIMITS
PEL (OSHA Permissible Exposure Limit) : None established for mixture, See Section II.
TLV (ACGIH Threshold Limit Value) :

None established for mixture, See Section II.

MSDS No. 108277
Date : 10/3/2005

Page3 of 6
HINO LLC EX SUPER
SECTION V - EMERGENCY FIRST AID PROCEDURE

For Overdose Exposure By :
Swallowing :

If victim is conscious and able to swallow, quickly have victim drink water or milk to
dilute. Do NOT give sodium bicarbonate, fruit juices or vinegar. NEVER give anything
by mouth if victim is unconscious or having convulsions. Induce vomiting only if
advised by physician or Poison Control Center. CALL PHYSICIAN OR POISON
CONTROL CENTER IMMEDIATELY.

Skin Contact :

Immediately flush skin with plenty of water while removing contaminated clothing.

Eye Contact :

Immediately flush eyes with plenty of cool water for at least 15 minutes. Do NOT
permit victim to rub eyes. GET MEDICAL ATTENTION IMMEDIATELY.

Inhalation :

Immediately remove victim to fresh air. If victim has stopped breathing give artificial
respiration, preferably mouth-to-mouth. GET MEDICAL ATTENTION
IMMEDIATELY.
SECTION VI - PHYSICAL DATA

Boiling Point :
Melting Point :
Vapor Pressure :
Density (20 C) :
Vapor Density (AIR = 1) :
pH (Original) :
Solubility in Water :
Appearance and Color :

108 C
(Freezing Point) less than 0 C
Estimated 0.05 mmHg at 20 C
1.08
Not determined
7.6
Infinite miscibility
Clear, slightly viscous, pink dyed dyed liquid

SECTION VII - FIRE AND EXPLOSION HAZARDS
Flash Point :

None

Auto-Ignition Temperature :

Not determined (400 C for ethylene glycol)

Flammable Limits in Air, %by Vol.
Lower :
Upper :

Not determined (3.2% for ethylene glycol)
Not determined (15.3% for ethylene glycol)

NFPA Rating :

Health ( 1 ) Fire ( 0 ) Reactivity ( 0 )

Fire Fighting Procedures :

(Note: Individuals should perform only those firefighting
procedures for which they have been trained.) Use water spray,
dry chemical, foam or carbon dioxide. Use water to keep
fire-exposed containers cool. If a spill or leak has not ignited, use
water pray to disperse the vapors. Water spray may be used to
flush spills away from fire and diluted spills to noncombustible
proportions (see warning on water spray on hot glycol below).

MSDS No. 108277
Date : 10/3/2005

Page4 of 6
HINO LLC EX SUPER

SECTION VII - FIRE AND EXPLOSION HAZARDS (CONTINUED)
Unusual Fire & Explosion Hazards :

Fire fighters should wear self-contained breathing apparatus in
the positive pressure mode with a full face piece when, there is a
possibility of exposure to smoke, fumes or hazardous
decomposition products. Water spray may cause foaming of hot
glycol so indirect application of water spray or use of other
extinguishing media should be used on hot glycol.

SECTION VIII - REACTIVITY
Stability :

Generally stable

Hazardous Polymerization :

Not likely to occur

Conditions and Materials to Avoid:

Avoid concentrated strong acids, oxidizing agents and bases. Do
not expose to open flame.

Hazardous Decomposition Products :

If pyrolyzed, thermal decomposition products of residue may
include C, CO, CO2, H2O, NH3, organic vapors and
nitrogen-containing.

SECTION IX - EMPLOYEE PROTECTION
Control Measures :

Handle in the presence of adequate ventilation. Engineering controls should
be used whenever feasible to maintain concentrations below acceptable
exposure criteria (see Section II and IV), including enclosures and local
exhaust ventilation.

Respiratory Protection :

Where exposure is likely to exceed acceptable criteria (see Section II and IV)
and engineering controls are not feasible, use NOSH/MISHA approved
respiratory protection equipment. Respirators should be selected based on the
form and concentration of contaminants in air and in accordance with OSHA
(29 CFR 1910.134).

Protective Clothing :

Wear gloves and protective clothing which are impervious to the product for
the duration of exposure if there is potential for skin contact.

Eye Protection :

Wear safety glasses meeting the specifications of ANSI standard Z87.1 where
no contact with the eye is anticipated. Chemical safety goggles meeting the
specification of ANSI Standard Z87.1 should be worn whenever there is the
possibility of splashing or other contact with the eyes.

MSDS No. 108277
Date : 10/3/2005

Page5 of 6
HINO LLC EX SUPER
SECTION X - ENVIRONMENTAL PROTECTION

Environmental Precautions :

Avoid uncontrolled releases of this material. Where spills are possible, a
comprehensive spill release response plan should be developed and
implemented.

Spill or Leak Procedures:

Wear appropriate respiratory equipment and protective equipment as
described in Section IX. Contain spilled material. Transfer to secure
containers. Where necessary, collect using absorbent media. In the event
of an uncontrolled release is reportable under the applicable laws and
regulations.

Waste Disposal :

All recovered material should be packaged, labeled, transported, and
disposed of or reclaimed in conformance with good engineering practices.
Avoid land filling of liquids. Reclaim where possible.
SECTION XI - REGULATORY CONTROLS

Department of Transportation :
DOT Classification(Bulk) :
DOT Proper Shipping Name :
DOT Classification (Non-bulk) :
IATA (Non-bulk) :
IMDG Code (Non-bulk) :

Class 9 miscellaneous
Environmentally Hazardous Substance Liquid n.o.s.
(ethylene glycol), 9, UN3082, III
Not regulated
Not regulated
Not regulated

Other Regulatory Requirements :
Toxic Substance Control Act :
This product is a mixture: therefore, it is not listed in the TSCA Inventory of
Chemical Substances. All of the components of the mixture are listed in the TSCA
Inventory of Chemical Substances.
SARA Hazard Categories (as defined in Section 311/312)
Immediate(Acute) and Delayed (Chronic)
Health
Physical
None
The product contains greater than 45 % ethylene glycol (CAS #107-21-1) which is
subject to the reporting requirements of Section 313 of Title III of the Superfund
Amendments and Reauthorization Act of 1986 and 40 CFR part 372.
California Proposition 65 :
This product does not contain any substances currently listed under California
Proposition 65.

MSDS No. 108277
Date : 10/3/2005

Page6 of 6
HINO LLC EX SUPER

SECTION XII - PRECAUTIONS: HANDLING, STORAGE AND USAGE
- To prevent possible storage container rupture, do not permit to freeze; See section VI.
- Do not expose children and pets to this material.
- Keep container closed.
- Keep away from open flames
- After handling product, wash thoroughly with soap and water before drinking, eating, or
smoking.
- Container hazardous when emptied. Since emptied containers retain product residues, all
hazardous precautions described on this MSDS must be observed.
SECTION XIII - CONTACT INFORMATION
The information presented herein is believed to be factual as it has been derived from the works and
opinions of people believed to be qualified experts; however, nothing contained in this information is to
be taken as a warranty or representation for which CCI Manufacturing IL Corporation bears legal
responsibility. The user should review any recommendation in the specific context of intended use to
determine whether they are appropriate.
Prepared By

CCI MANUFACTURING IL CORPORATION

For further information contact :
Technical Manager
CCI MANUFACTURING IL CORPORATION
15550 Canal Bank Road.
Lemont, IL 60439
(630)-739-0606